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Angelina Jolie met Brad Pitt in the filming of Mr. and Mrs. Smith (2005), in which they play a couple of secret agents. The couple engaged the romance in real life the same year the film was released after the actor divorced Jennifer Aniston - many even accused Brad of treason, which is denied by the heartthrob to this day. After many years together and with the family formed, the two married officially in 2014.