Brad Pitt and Jennifer Aniston were one of the most popular and happy Hollywood couples in the early 2000s but it all fell apart when Brad met Angelina Jolie while filming Mr. and Mrs. Smith in 2005. Even though we never saw any photos proving that Pitt was indeed cheating, the couple divorced soon after the rumors popped up and the rest is history. This was the third time Jolie was the one to blame for a happy couple breaking up (the first two were Billy Bob Thornton and Ethan Hawke).
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