Blue eyes don’t contain blue pigment, so it’s fair to say they aren’t really blue. They simply appear blue because the lack of melanin causes light to split into a color spectrum. This effect is known as Rayleigh scattering.
There is no actual blue pigment for eyes. People with brown eyes have them because melanin is a brown pigment. The result of this scattering of light is blue light hitting the top of the iris. This gives the eyes their blue appearance.
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